15,023 research outputs found

    Scaling of broadband dielectric data of glass-forming liquids and plastic crystals

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    The Nagel-scaling and the modified scaling procedure proposed recently by Dendzik et al. have been applied to broadband dielectric data on two glass- forming liquids (glycerol and propylene carbonate) and three plastic crystals (ortho-carborane, meta-carborane, and 1-cyano-adamantane). Our data extend the upper limit of the abscissa range to considerably higher values than in previously published analyses. At the highest frequencies investigated, deviations from a single master curve show up which are most pronounced in the Dendzik-scaling plot. The loss curves of the plastic crystals do not scale in the Nagel-plot, but they fall onto a separate master curve in the Dendzik-plot. In addition, we address the question of a possible divergence of the static susceptibility near the Vogel-Fulcher temperature. For this purpose, the low-temperature evolution of the high-frequency wing of the dielectric loss peaks is investigated in detail. No convincing proof for such a divergence can be deduced from the present broadband data.Comment: 7 pages including 6 figures submitted to Eur. Phys. J.

    The excess wing in the dielectric loss of glass-forming ethanol: A relaxation process

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    A detailed dielectric investigation of liquid, supercooled liquid, and glassy ethanol reveals a third relaxation process, in addition to the two processes already known. The relaxation time of the newly detected process exhibits strong deviations from thermally activated behavior. Most important, this process is the cause of the apparent excess wing, which was claimed to be present in the dielectric loss spectra of glass-forming ethanol. In addition, marked deviations of the spectra of ethanol from the scaling proposed by Dixon and Nagel have been detected.Comment: 8 pages including 4 figures submitted to Phys. Rev.

    The Excess Wing in the Dielectric Loss of Glass-Formers: A Johari-Goldstein beta-Relaxation?

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    Dielectric loss spectra of glass-forming propylene carbonate and glycerol at temperatures above and below T_g are presented. By performing aging experiments lasting up to five weeks, equilibrium spectra below T_g have been obtained. During aging, the excess wing, showing up as a second power law at high frequencies, develops into a shoulder. The results strongly suggest that the excess wing, observed in a variety of glass formers, is the high-frequency flank of a beta-relaxation.Comment: submitted to Phys. Rev. Lett., 4 figures, revised version after referee report

    Cantilever-based Resonant Microsensors with Integrated Temperature Modulation for Transient Chemical Analysis

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    This work introduces a resonant cantilever platform with integrated temperature modulation for real-time chemical sensing. Embedded heaters allow for rapid thermal cycling of individual sensors, thereby enabling real-time transient signal analysis without the need for a microfluidic setup to switch between analyte and reference gases. Compared to traditional mass-sensitive microsensors operating in steady state, the on-chip generation of signal transients provides additional information for analyte discrimination

    Compressed Genotyping

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    Significant volumes of knowledge have been accumulated in recent years linking subtle genetic variations to a wide variety of medical disorders from Cystic Fibrosis to mental retardation. Nevertheless, there are still great challenges in applying this knowledge routinely in the clinic, largely due to the relatively tedious and expensive process of DNA sequencing. Since the genetic polymorphisms that underlie these disorders are relatively rare in the human population, the presence or absence of a disease-linked polymorphism can be thought of as a sparse signal. Using methods and ideas from compressed sensing and group testing, we have developed a cost-effective genotyping protocol. In particular, we have adapted our scheme to a recently developed class of high throughput DNA sequencing technologies, and assembled a mathematical framework that has some important distinctions from 'traditional' compressed sensing ideas in order to address different biological and technical constraints.Comment: Submitted to IEEE Transaction on Information Theory - Special Issue on Molecular Biology and Neuroscienc

    Unified powered flight guidance

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    A complete revision of the orbiter powered flight guidance scheme is presented. A unified approach to powered flight guidance was taken to accommodate all phases of exo-atmospheric orbiter powered flight, from ascent through deorbit. The guidance scheme was changed from the previous modified version of the Lambert Aim Point Maneuver Mode used in Apollo to one that employs linear tangent guidance concepts. This document replaces the previous ascent phase equation document
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